Ce–Fe–O системы, полученные методом растворного горения в присутствии оксида алюминия и кремния, и их эффективность в гидрировании CO2 до синтез-газа
https://doi.org/10.17586/2220-8054-2023-14-6-679-689
Аннотация
В настоящей работе представлены Ce–Fe–O системы, нанесенные на γ-Al2O3 или SiO2, для повышения реакционной способности кислородно-дефицитной фазы перовскита CeFeO3, которые являются перспективными катализаторами для производства топлива и химикатов из CO2. Синтез проводился методом растворного горения при различных отношениях горючего (глицина) и окислителя, с добавлением или без добавления нитрата аммония. Полученные композиты были охарактеризованы методами РФА, СЭМ, ЭДС, N2-физосорбции, H2-ТПВ и CO2-ТПД для выявления связи физико-химических свойств с каталитической активностью в гидрировании CO2. γ-Al2O3 оказался более подходящим носителем, чем SiO2, благодаря его способности образовывать более высокое содержание перовскита, уменьшать размер кристаллитов CeFeO3, увеличивать кислородную дефектность и адсорбционную способность CO2. Горение в присутствии кремнезема приводит к связыванию большей части церия в силикатную фазу, которая неактивна для реакции сдвига водяного газа.
Об авторах
А. Н. Матвеева
Ioffe Institute
Россия
Россия
Ш. О. Омаров
Ioffe Institute
Россия
Россия
М. А. Гаврилова
Ioffe Institute; St.-Petersburg State Institute of Technology (Technical University)
Россия
Россия
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Рецензия
Для цитирования:
Матвеева А.Н., Омаров Ш.О., Гаврилова М.А. Ce–Fe–O системы, полученные методом растворного горения в присутствии оксида алюминия и кремния, и их эффективность в гидрировании CO2 до синтез-газа. Наносистемы: физика, химия, математика. 2023;14(6):679-689. https://doi.org/10.17586/2220-8054-2023-14-6-679-689
For citation:
Matveyeva A.N., Omarov Sh.O., Gavrilova M.A. Alumina and silica supported Ce–Fe–O systems obtained by the solution combustion method and their performance in CO2 hydrogenation to syngas. Nanosystems: Physics, Chemistry, Mathematics. 2023;14(6):679-689. https://doi.org/10.17586/2220-8054-2023-14-6-679-689
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