Фазообразование и термический анализ в системе LaPO4-GdPO4-H2O
М. О. Еникеева,
К. А. Жидоморова,
Д. П. Данилович,
В. Н. Неведомский,
О. В. Проскурина,
В. В. Гусаров https://doi.org/10.17586/2220-8054-2024-15-6-781-792
Аннотация
Исследованы структурные трансформации нанокристаллов в оксидной системе LaPO4-GdPO4-(H2O) в гидротермальных условиях при 230°C в зависимости от продолжительности изотермической выдержки (2 часа, 3 суток и 5 суток). Показано, что в системе до гидротермальной обработки кристаллизуется фаза со структурой рабдофана
La1-xGdxPO4·nH2O (0.00≤x≤1.00) со средневзвешенным значением размеров кристаллитов
4-7 нм. В результате гидротермальной обработки образцы в системе LaPO4-GdPO4-(H2O) полностью трансформируются в фазу со структурой монацита за пять суток, медленнее всего процесс трансформации наблюдается для ортофосфата гадолиния. Определено, что наночастицы со структурой рабдофана GdPO4·nH2O имею монокристаллическое строение. Методом синхронного термического анализа показано, что образцы, полученные методом осаждения, содержат рентгеноаморфную фазу и примесные соединения, температура структурного превращения рабдофан→монацит и количество молекул воды в структуре рабдофана зависит от химического состава соединения при изоморфном замещении катиона лантана на катион гадолиния.
Об авторах
М. О. Еникеева
Ioffe Institute; Branch of Petersburg Nuclear Physics Institute named after B. ˙P. Konstantinov of National Research Centre “Kurchatov Institute” – Institute of Silicate Chemistry
Россия
Россия
К. А. Жидоморова
Branch of Petersburg Nuclear Physics Institute named after B. ˙P. Konstantinov of National Research Centre “Kurchatov Institute” – Institute of Silicate Chemistry; St. Petersburg State Institute of Technology
Россия
Россия
Д. П. Данилович
St. Petersburg State Institute of Technology
Россия
Россия
В. Н. Неведомский
Ioffe Institute
Россия
Россия
О. В. Проскурина
Ioffe Institute; St. Petersburg State Institute of Technology
Россия
Россия
В. В. Гусаров
Ioffe Institute
Россия
Россия
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Для цитирования:
Еникеева М.О., Жидоморова К.А., Данилович Д.П., Неведомский В.Н., Проскурина О.В., Гусаров В.В. Фазообразование и термический анализ в системе LaPO4-GdPO4-H2O. Наносистемы: физика, химия, математика. 2024;15(6):781-792. https://doi.org/10.17586/2220-8054-2024-15-6-781-792
For citation:
Enikeeva M.O., Zhidomorova K.A., Danilovich D.P., Nevedomskiy V.N., Proskurina O.V., Gusarov V.V. Phase formation and thermal analysis in the LaPO4–GdPO4–H2O system. Nanosystems: Physics, Chemistry, Mathematics. 2024;15(6):781-792. https://doi.org/10.17586/2220-8054-2024-15-6-781-792
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