Интерметаллиды, полученные из гидрогерманатов Me3Ge2O5(OH)4 (Me = Mg, Ni, Fe, Co): синтез однофазных прекурсоров
https://doi.org/10.17586/2220-8054-2024-15-6-821-836
Аннотация
Обычно интерметаллиды получают твердофазным методом при высоких температурах. В данной работе предложен простой метод получения интерметаллидов путем восстановления из прекурсоров в атмосфере Ar-H2. Окисление Co2+ и Fe2+ в гидротермальных условиях представляет собой дополнительную экспериментальную задачу. В данной работе мы впервые сообщаем об успешном синтезе Fe-гидрогерманата. Выявлены общие закономерности образования гидрогерманатов и определено влияние гидротермальной обработки на фазовый состав и морфологию для всего ряда гидрогерманатов. Образование гидрогерманатов в гидротермальных условиях изучалось в диапазоне температур 100-200 ℃ в трех гидротермальных средах: H2O, NaOH, Na2SO3. Последняя ингибировала окисление Co2+ и Fe2+ во время синтеза. Повышение температуры способствовало образованию фазы, описываемой трехслойной элементарной ячейкой. Термическая обработка в атмосфере Ar-H2 позволила получить интерметаллиды и сплавы MexGey, а также установить температурные режимы восстановительных процессов.
Об авторах
Е. К. Храпова
Ioffe Institute
Россия
Россия
А. А. Иванова
Ioffe Institute
Россия
Россия
Д. А. Кириленко
Ioffe Institute
Россия
Россия
А. А. Красилин
Ioffe Institute
Россия
Россия
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Рецензия
Для цитирования:
Храпова Е.К., Иванова А.А., Кириленко Д.А., Красилин А.А. Интерметаллиды, полученные из гидрогерманатов Me3Ge2O5(OH)4 (Me = Mg, Ni, Fe, Co): синтез однофазных прекурсоров. Наносистемы: физика, химия, математика. 2024;15(6):821-836. https://doi.org/10.17586/2220-8054-2024-15-6-821-836
For citation:
Khrapova E.K., Ivanova A.A., Kirilenko D.A., Krasilin A.A. Intermetallic compounds obtained from Me3Ge2O5(OH)4 (Me = Mg, Ni, Fe, Co) phyllogermanates: synthesis of single-phase precursors. Nanosystems: Physics, Chemistry, Mathematics. 2024;15(6):821-836. https://doi.org/10.17586/2220-8054-2024-15-6-821-836
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