Chemical looping methane dry reforming over Ni-containing modified ceria-zirconia
https://doi.org/10.17586/2220-8054-2024-15-6-879-892
Abstract
Modified ceria-zirconia oxides were prepared in supercritical fluids in flow-type installation. Ni was added by wetness impregnation. All materials were studied by a complex of physicochemical techniques (XRD, TEM, H2-TPR). Catalysts have been investigated in a modern process – chemical looping methane dry reforming (CLMDR). Conversions of CH4 and CO2, H2/CO ratio, H2 and CO productivities were calculated. The features of CLMDR process were compared with results obtained in MDR steady-state conditions.
Supporting agencies: This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental assignment for Boreskov Institute of Catalysis (project FWUR-2024-0033). The studies were carried out using the facilities of the shared research center “National Center of Investigation of Catalysts” at Boreskov Institute of Catalysis. Authors thank to T. Krieger and O. Bulavchenko for XRD, V. Rogov for H2-TPR and A. Ishchenko for TEM studies.
About the Authors
E. Smal
Boreskov Institute of Catalysis SB RAS
Russian Federation
Russian Federation
Ekaterina Smal
630090, Lavrentieva prospect, 5, Novosibirsk
V. Fedorova
Boreskov Institute of Catalysis SB RAS
Russian Federation
Russian Federation
Valeria Fedorova
630090, Lavrentieva prospect, 5, Novosibirsk
K. Valeev
Boreskov Institute of Catalysis SB RAS
Russian Federation
Russian Federation
Konstantin Valeev
630090, Lavrentieva prospect, 5, Novosibirsk
A. Hassan
Novosibirsk State University
Russian Federation
Russian Federation
Amir Hassan
630090, Pirogova st., 1, Novosibirsk
E. Gerasimov
Boreskov Institute of Catalysis SB RAS
Russian Federation
Russian Federation
Evgeny Gerasimov
630090, Lavrentieva prospect, 5, Novosibirsk
M. Simonov
Boreskov Institute of Catalysis SB RAS
Russian Federation
Russian Federation
Mikhail Simonov
630090, Lavrentieva prospect, 5, Novosibirsk
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For citations:
Smal E., Fedorova V., Valeev K., Hassan A., Gerasimov E., Simonov M. Chemical looping methane dry reforming over Ni-containing modified ceria-zirconia. Nanosystems: Physics, Chemistry, Mathematics. 2024;15(6):879-892. https://doi.org/10.17586/2220-8054-2024-15-6-879-892
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