Near-field optical patterns of dielectric nanoparticles deposited on a metallic surface
https://doi.org/10.17586/2220-8054-2022-13-1-56-61
Аннотация
Spatial structures of electromagnetic near-fields generated by plasmonic resonances are studied through numerical simulations. Resonances can appear in silver nanoplates onto which nanoparticles of various shapes are deposited. For forthcoming biophysical applications, nanoparticles are considered here as irregular aggregates of grains made of DNA material. The Discrete Dipole Approximation technique is used to calculate the electromagnetic field profiles. In certain controlled physical situations, the plasmonic pattern appears to be the glowing anti-shadow of the deposited nanoparticle, and such a pattern locally produces strong increase in the electromagnetic fields. Even when the nanoparticle size is much smaller than the wavelength, fine (sub-wavelength) details of the anti-shadow are directly related to the shape of the nanoparticle. These observations should result in a better understanding of the Surface-Enhanced Raman Scattering process and an improvement in nanocharacterization techniques.
Список литературы
1. Pana X., Medina-Ramirez I., Mernaugh R., Liu J. Nanocharacterization and bactericidal performance of silver modified titania photocatalyst. Colloids and Surfaces B: Biointerfaces, 2010, 77, P. 82-89.
2. Gates B.D., Xu Q., et al. New approaches to nanofabrication: molding, printing, and other techniques. Chem. Rev., 2005, 105, P. 1171-1196.
3. Biswas A., Bayer I.S., et al. Advances in top-down and bottom-up surface nanofabrication: techniques, applications & future prospects. Advances in Colloid and Interface Science, 2012, 170, P. 2-27.
4. Gillet J.-N., Meunier M. General Equation for Size Nanocharacterization of the Core-Shell Nanoparticles by X-ray Photoelectron Spectroscopy. J. Phys. Chem. B, 2005, 109, P. 8733-8737.
5. Betzig E., Trautman J.K. Near-Field Optics: Microscopy, Spectroscopy, and Surface Modification Beyond the Diffraction Limit. Science, 1992, 257, P. 189-195.
6. Jeanmaire D.L., Van Duyne R.P. Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode. J. of Electroanalytical Chemistry and Interfacial Electrochemistry, 1977, 84, P. 1-20.
7. Albrecht M.G., Creighton J.A. Anomalously intense Raman spectra of pyridine at a silver electrode. J. Am. Chem. Soc., 1977, 99, P. 5215-5217.
8. Schatz G.C., Young M.A., Van Duyne R.P. Electromagnetic mechanism of SERS. In: Kneipp K., Moskovits M. & Kneipp H.(Eds.) Surface-Enhanced Raman Scattering - Physics and Applications. Topics Apl. Phys., 2006, 103, P. 19-46.
9. Stiles P.L., Dieringer J.A., Shah N.C., Van Duyne R.P. Surface-enhanced Raman spectroscopy. Annu. Rev. Anal. Chem., 2008, 1, P. 601-626.
10. Zhu J., Goddard L.L. All-dielectric concentration of electromagnetic fields at the nanoscale: the role of photonic nanojets. Nanoscale Adv., 2019, 1, P. 4615-4643.
11. Jia Y., Li R., Zhuanga W., Liang J. Photonic nanojet generated by a spheroidal particle illuminated by a vector Bessel beam. Results in Optics, 2021, 4, 100106.
12. Purcell E.M., Pennypacker C.R. Scattering and absorption of light by nonspherical dielectric grains. Astrophys. J., 1973, 186, P. 705-714.
13. Draine B.T. The discrete-dipole approximation and its application to interstellar graphite grains. Astrophys. J., 1988, 333, P. 848-872.
14. Draine B.T. The Discrete Dipole Approximation for Scattering and Absorption of Light by Irregular Particles. URL: https://www.astro.princeton.edu/˜draine/DDSCAT.7.3.html.
15. Anderson M.S. Enhanced infrared absorption with dielectric nanoparticles. Appl. Phys. Lett., 2003, 83, P. 2964-2966.
16. Zybin A., Kuritsyn Y.A., et al. Real-time Detection of Single Immobilized Nanoparticles by Surface Plasmon Resonance Imaging. Plasmonics, 2009, 5 (1), P. 31-35.
17. Braun G., Lee S.J., et al. Surface-Enhanced Raman Spectroscopy for DNA Detection by Nanoparticle Assembly onto Smooth Metal Films. J. Am. Chem. Soc., 2007, 129, P. 6378-6379.
18. Shalaev V.M., Botet R., Mercer J., Stechel E.B. Optical properties of self-affine thin films. Phys. Rev. B, 1996, 54, P. 8235-8242.
19. Jullien R., Botet R. Aggregation and Fractal Aggregates. World Scientific Publishing, Singapore, 1987, 130 p.
20. Meakin P., Jullien R. The effects of restructuring on the geometry of clusters formed by diffusion-limited, ballistic, and reaction-limited cluster-cluster aggregation. J. Chem. Phys., 1988, 89, P. 246-250.
21. Rai R.K., Rastogi S., Botet R. Effect of grain shape on extinction using effective medium theory. Asian J. of Physics, 2015, 24, P. 1097-1103.
22. Rai R.K., Botet R.S. Monthly Notices of the Royal Astron. Society, 2014, 444, P. 303-312.
23. Draine B.T., Goodman J. Beyond Clausius-Mossotti - Wave propagation on a polarizable point lattice and the discrete dipole approximation. Astrophys. J., 1993, 405, P. 685-697.
24. Abdulhalim I. Coupling configurations between extended surface electromagnetic waves and localized surface plasmons for ultrahigh field enhancement. Nanophotonics, 2018, 7 (12), P. 1891-1916.
25. Inagaki T., Hamm R.N., Arakawa E.T. Optical and dielectric properties of DNA in the extreme ultraviolet, The J. of Chemical Physics, 1974, 61, P. 4246-4250.
26. Pedersen J.S. Analysis of small-angle scattering data from colloids and polymer solutions: modeling and least-squares fitting. Advances in Colloid and Interface Science, 1997, 70, P. 171-210.
27. Oshikane Y., Kataoka T., et al. Observation of nanostructure by scanning near-field optical microscope with small sphere probe. Science and Technology of Advanced Materials, 2007, 8, P. 181-185.
Рецензия
Для цитирования:
, . Наносистемы: физика, химия, математика. 2022;13(1):56-61. https://doi.org/10.17586/2220-8054-2022-13-1-56-61
For citation:
Rai R.K., Botet R.S. Near-field optical patterns of dielectric nanoparticles deposited on a metallic surface. Nanosystems: Physics, Chemistry, Mathematics. 2022;13(1):56-61. https://doi.org/10.17586/2220-8054-2022-13-1-56-61