Synthesis, characterization and electrical properties of the nanosized perovskite LaFeO3
https://doi.org/10.17586/2220-8054-2022-13-2-181-191
Abstract
Single-phase highly crystalline LaFeO3 is synthesized by autocombustion of the gel complex obtained from citrate and metal nitrate precursors. The XRD analysis exhibited the transformation of amorphous phases of La2O3 and Fe2O3 into highly crystalline LaFeO3 at 1000 ◦C. The agglomerated semi spherical morphology is observed. The average particle size of sintered pellets at 1000 ◦C for 4 h, 8, 12, and 16 h heating time is found 105, 130, 160 and 200 nm, respectively. TGA analysis revealed 27% weight lost due to the decomposition of La(OH)3 and Fe(OH)3 into La2O3, Fe2O3 , and LaFeO3. Electrical properties of LaFeO3 were found to be dependent on micro-structural heterogeneities i.e., grain and grain boundaries. Two probe DC resistivity exhibited decrease in resistance with increasing heat treatment and time. The outcomes of this study confirmed the potential applications of perovskite-type LaFeO3 in energy and environmental sectors.
About the Authors
Muhammad Irfan Ashgar
COMSATS University Islamabad
Russian Federation
Russian Federation
Muhammad Kashif Shahid
Chungnam National University
Russian Federation
Russian Federation
Muhammad Haq Nawaz
University of Gujrat
Russian Federation
Russian Federation
Muhammad Idrees
COMSATS University Islamabad
Russian Federation
Russian Federation
Muhammad Asif
University of Engineering and Technology Lahore
Russian Federation
Russian Federation
Ahsan Ali
University of Leeds
Russian Federation
Russian Federation
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Review
For citations:
Ashgar M.I., Shahid M.K., Nawaz M.H., Idrees M., Asif M., Ali A. Synthesis, characterization and electrical properties of the nanosized perovskite LaFeO3. Nanosystems: Physics, Chemistry, Mathematics. 2022;13(2):181-191. https://doi.org/10.17586/2220-8054-2022-13-2-181-191
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