Mechanism of formation of nanocrystalline particles with core-shell structure based on titanium oxynitrides with nickel in the process of plasma-chemical synthesis of TiNi in a low-temperature nitrogen plasma
https://doi.org/10.17586/2220-8054-2022-13-2-212-219
Аннотация
This paper presents the results of experiments, structural and morphological certification and modeling of ultrafine and nanocrystalline TiN-Ni “core-shell“ structures obtained during plasma-chemical synthesis of industrially manufactured microcrystalline TiNi. Experiments on plasma-chemical synthesis were carried out by recondensation of ultrafine and nanocrystalline powders in a rotating cylinder of gaseous nitrogen. X- ray phase analysis and high-resolution transmission electron microscopy (HR TEM) showed the presence of refractory titanium compounds with nitrogen and metallic nickel, which are part of the core-shell structures, including the metastable, highly deformed complex nitride Ti0.7Ni0 . 3N of hexagonal modification. HR TEM studies showed the localization of phases determined by X-ray diffraction and confirmed the “core-shell” structure on the example of nanocrystalline TiN-Ni fraction. Based on the experimental results, we have developed a model of crystallization of TiN-Ni “core-shell“ structures under the conditions of a rotating cylinder of gaseous nitrogen, where the crystallization rate is 105 ◦C/s.
Об авторах
Yu. Avdeeva
Institute of Solid State Chemistry
Россия
Россия
I. Luzhkova
Institute of Solid State Chemistry
Россия
Россия
A. Ermakov
Institute of Solid State Chemistry
Россия
Россия
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Рецензия
Для цитирования:
, , . Наносистемы: физика, химия, математика. 2022;13(2):212-219. https://doi.org/10.17586/2220-8054-2022-13-2-212-219
For citation:
Avdeeva Yu.A., Luzhkova I.V., Ermakov A.N. Mechanism of formation of nanocrystalline particles with core-shell structure based on titanium oxynitrides with nickel in the process of plasma-chemical synthesis of TiNi in a low-temperature nitrogen plasma. Nanosystems: Physics, Chemistry, Mathematics. 2022;13(2):212-219. https://doi.org/10.17586/2220-8054-2022-13-2-212-219
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