Impact of sensitizer Yb and activator Tm on luminescence intensity of β -NaYF4:Yb/Tm nanoluminophores
https://doi.org/10.17586/2220-8054-2022-13-3-331-341
Abstract
In this study, the impact of sensitizer and activator ions concentration on the intensity of up-conversion luminescence of nanoluminophores β-NaYF4:Yb3+/Tm3+ in dimethyl sulfoxide (DMSO) was investigated. Analysis of all luminescence spectral bands allows one to establish that the ratio of concentrations of ytterbium and thulium ions strongly effects on the luminescent properties of nanoluminophores. Increase of sensitizer concentration at constant activator concentration leads to an increase of the luminescence integral intensity. Optimal concentration of activators at fixed sensitizer concentration was determined: 2 mol.% for thulium and 18 mol.% for ytterbium. The sensitivity of each luminescence spectrum band to changes in the concentration of activators and sensitizers was explained by cross-relaxation processes in activator ions.
About the Authors
S. V. Kuznetsov
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
S. A. Burikov
Lomonosov Moscow State University
Russian Federation
Russian Federation
A. A. Fedyanina
Lomonosov Moscow State University
Russian Federation
Russian Federation
E. A. Filippova
Lomonosov Moscow State University
Russian Federation
Russian Federation
V. Yu. Proydakova
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
V. V. Voronov
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
N. Yu. Tabachkova
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
P. P. Fedorov
Prokhorov General Physics Institute of the Russian Academy of Sciences
Russian Federation
Russian Federation
T. A. Dolenko
Lomonosov Moscow State University
Russian Federation
Russian Federation
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Review
For citations:
Kuznetsov S.V., Burikov S.A., Fedyanina A.A., Filippova E.A., Proydakova V.Yu., Voronov V.V., Tabachkova N.Yu., Fedorov P.P., Dolenko T.A. Impact of sensitizer Yb and activator Tm on luminescence intensity of β -NaYF4:Yb/Tm nanoluminophores. Nanosystems: Physics, Chemistry, Mathematics. 2022;13(3):331-341. https://doi.org/10.17586/2220-8054-2022-13-3-331-341
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