Photochromic aerogels based on cellulose and chitosan modified with WO3 nanoparticles
https://doi.org/10.17586/2220-8054-2022-13-4-404-413
Аннотация
In this work, we report the first synthesis of photochromic aerogels and films based on TEMPO-oxidized cellulose and chitosan modified with tungsten trioxide nanoparticles. The blue coloring of aerogels based on WO3-modified biopolymers under UV light occurs due to the reduction of W+6 to W+5. The coloration of films of the same composition occurs due to the reduction of W+6 to W+5 and W+4. The photochromic properties of aerogels and films are reversible; oxidation by atmospheric oxygen leads to bleaching of materials. At that, films become colorless within a few days while aerogels with a high specific surface area (200 m2/g) become colorless within several minutes. The antioxidant properties of the WO3 sol and the WO3/TEMPO-oxidized cellulose/chitosan composite were studied by luminol-activated chemiluminescence method. The antioxidant capacity of WO3/TEMPO-oxidized cellulose/chitosan gel is 1.5 times higher than that of the commercially available antioxidant mexidol.
Ключевые слова
Aerogel,
hybrid materials,
nanocomposite,
biopolymers,
cellulose,
chitosan,
tungsten oxide,
photochromic material,
antioxidant
Об авторах
S. Kameneva
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
M. Popkov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Lomonosov Moscow State University
Россия
Россия
I. Tronev
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; HSE University
Россия
Россия
S. Kottsov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Lomonosov Moscow State University
Россия
Россия
M. Sozarukova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
V. Ivanov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
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Рецензия
Для цитирования:
, , , , , . Наносистемы: физика, химия, математика. 2022;13(4):404-413. https://doi.org/10.17586/2220-8054-2022-13-4-404-413
For citation:
Kameneva S.V., Popkov M.A., Tronev I.V., Kottsov S.Yu., Sozarukova M.M., Ivanov V.K. Photochromic aerogels based on cellulose and chitosan modified with WO3 nanoparticles. Nanosystems: Physics, Chemistry, Mathematics. 2022;13(4):404-413. https://doi.org/10.17586/2220-8054-2022-13-4-404-413
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