Formation of nanocrystalline particles on the basis of La2(Ni,Mn,Fe)2O6 variable composition phases having a structure of double perovskite under conditions of solution combustion
https://doi.org/10.17586/2220-8054-2022-13-6-655-661
Abstract
Nanocrystalline particles on the basis of La2(Ni,Mn,Fe)2O6 variable composition phases of a double perovskite structure have been produced by glycine-nitrate combustion. The size of crystallites grows from 5 to 45 nm with an increase in iron content of synthesized particles. It is demonstrated that iron unevenly builds into octahedral sites of nickel and manganese ions substituting mainly manganese ions. At the same time, the dependence of double perovskite unit cell volume on the iron ions concentration is well described by Retgers’ law.
About the Authors
D. D. Averkiev
Ioffe Institute; St. Petersburg State Electrotechnical University “LETI”
Russian Federation
Russian Federation
L. L. Larina
Emanuel Institute of Biochemical Physics
Russian Federation
Russian Federation
O. I. Shevaleevskiy
Emanuel Institute of Biochemical Physics
Russian Federation
Russian Federation
O. V. Almjasheva
Ioffe Institute; St. Petersburg State Electrotechnical University “LETI”
Russian Federation
Russian Federation
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For citations:
Averkiev D.D., Larina L.L., Shevaleevskiy O.I., Almjasheva O.V. Formation of nanocrystalline particles on the basis of La2(Ni,Mn,Fe)2O6 variable composition phases having a structure of double perovskite under conditions of solution combustion. Nanosystems: Physics, Chemistry, Mathematics. 2022;13(6):655-661. https://doi.org/10.17586/2220-8054-2022-13-6-655-661
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