SILD synthesis of porous manganese oxide nanocoatings as electroactive materials for pseudocapacitors
https://doi.org/10.17586/2220-8054-2023-14-5-554-559
Abstract
In present work the porous nanocoating of manganese oxide were obtained via successive ionic layer deposition from aqueous solutions of potassium permanganate and DMSO. The morphology, phase and chemical composition of the synthesized nanocoatings were characterized by XRD, SEM, EDX and Raman spectroscopy. The possibility of controlled changes in the morphology of the resulting compounds was demonstrated by changing the concentration of reagents and the number of processing cycles in order to obtain optimal electrochemical characteristics. Electrodes based on nickel foam and coated with films of porous manganese oxide showed high specific capacity (1324 and 297 F/g at a current density of 1 A/g in 1 M NaOH and 1 M Na2SO4, respectively), both in neutral and in aqueous alkaline electrolytes.
Supporting agencies: This research was financial supported by grant of the President of the Russian Federation for state support of young Russian scientists (grant number MK-3864.2022.1.3). The SEM and PXRD study was conducted utilizing equipment at the Engineering Center of the St. Petersburg State Institute of Technology. The authors gratefully acknowledge to the Center for Optical and Laser Materials Research of St. Petersburg State University.
About the Authors
A. A. Lobinsky
Ioffe Institute
Russian Federation
Russian Federation
Artem A. Lobinsky
Saint Petersburg, 194021
M. V. Kaneva
Ioffe Institute
Russian Federation
Russian Federation
Maria V. Kaneva
Saint Petersburg, 194021
A. K. Bachina
Ioffe Institute
Russian Federation
Russian Federation
Anastasia K. Bachina
Saint Petersburg, 194021
M. I. Tenevich
Ioffe Institute
Russian Federation
Russian Federation
Maxim I. Tenevich
Saint Petersburg, 194021
References
1. Liu C., Li F., Ma L.-P., Cheng H.-M. Advanced Materials for Energy Storage. Adv. Mater., 2010, 22, P. 28–62.
2. Zhou G., Li F., Cheng H.-M. Progress in flexible lithium batteries and future prospects. Energy Environ. Sci., 2014, 7, P. 1307–1338.
3. Wang G., Zhang L., Zhang J. A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev., 2012, 41, P. 797–828.
4. Zhong C., Deng Y., Hu W., Qiao J., Zhang L., Zhang J. A review of electrolyte materials and compositions for electrochemical supercapacitors. Chem. Soc. Rev., 2015, 44, P. 7484–7539.
5. Bhojane P. Recent advances and fundamentals of Pseudocapacitors: Materials, mechanism, and its understanding. J. Energy Storage, 2022, 45, 103654.
6. Sahin M., Blaabjerg F., Sangwongwanich A. A Comprehensive Review on Supercapacitor Applications and Developments. Energies (Basel), 2022, 15 (3), P. 674–699.
7. Wei W., Cui X., Chen W., Ivey D.G. Manganese oxide-based materials as electrochemical supercapacitor electrodes. Chem. Soc. Rev., 2011, 40, P. 1697–1721.
8. Simin He, Zunli Mo, Chao Shuai, Wentong Liu, Ruimei Yue, Guigui Liu, Hebing Pei, Ying Chen, Nijuan Liu, Ruibin Guo. Pre-intercalation -MnO2 zinc-ion hybrid supercapacitor with high energy storage and ultra-long cycle life. Applied Surface Science, 2022, 577, 151904.
9. Gao Y.N., Yang H.Y., Bai Y., Wu C. Mn-based oxides for aqueous rechargeable metal ion batteries. J. Mater. Chem. A, 2021, 9, P.11472–11500.
10. Julien C., Mauger A. Nanostructured MnO2 as electrode materials for energy storage. Nanomaterials, 2017, 7, 396.
11. Subramanian V., Zhu H., Vajtai R., Ajayan P.M., Wei B. Hydrothermal synthesis and pseudocapacitance properties of MnO2 nanostructures. J. Phys. Chem. B, 2005, 109, P. 20207–20214.
12. Hashem A.M., Abdel-Ghany A.E., El-Tawil R., Bhaskar A., Hunzinger B., Ehrenberg H., Mauger A., Julien C.M. Urchin-like -MnO2 formed of nano-needles for high-performance lithium batteries. Ionics, 2016, 22, P. 2263–2271.
13. Yin B., Zhang S., Jiang H., Qu F.,Wu X. Phase-controlled synthesis of polymorphic MnO2 structures for electrochemical energy storage. J. Mater. Chem., 2015, 3, P. 5722–5729.
14. Alfaruqi M.H., Gim J., Kim S., Song J., Kim J. A layered -MnO2 nanoflake cathode with high zinc-storage capacities for eco-friendly battery applications. Electrochem. Commun., 2015, 60, P. 121–125.
15. Cui H.J., Huang H.Z., Fu M.L., Yuan B.L., Pearl W. Facile synthesis and catalytic properties of single crystalline -MnO2 nanorods. Catal. Commun., 2011, 12, P. 1339–1343.
16. Kumar H., Sangwan M., Sangwan P. Synthesis and characterization of MnO2 nanoparticles using co-precipitation technique. Int. J. Chem. Chem. Eng., 2013, 3, P. 155–160.
17. Samantha Prabath Ratnayake, Jiawen Ren, Elena Colusso, Massimo Guglielmi, Alessandro Martucci, Enrico Della Gaspera. SILAR deposition of metal oxide nanostructured films. Small, 2021, 2101666.
18. Tolstoy V.P. Successive ionic layer deposition. The use in nanotechnology Russ. Chem. Rev., 2006, 75, P. 161.
19. Ragupathy P., Vasan H.N., Munichandraiah N. Synthesis and characterization of nano-MnO2 for electrochemical supercapacitor studies. J. Electrochem. Soc., 2008, 155, P. 34–40.
20. Kodintsev I.A., Martinson K.D., Lobinsky A.A., Popkov V.I. SILD synthesis of the efficient and stable electrocatalyst based on CoO-NiO solid solution toward hydrogen production. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10 (6), P. 681–685.
21. Kodintsev I.A., Martinson K.D., Lobinsky A.A., Popkov V.I. Successive ionic layer deposition of co-doped Cu(OH)2 nanorods as electrode material for electrocatalytic reforming of ethanol. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10 (5), P. 573–578.
22. Lobinsky A.A., Kaneva M.V. Synthesis Ni-doped CuO nanorods via successive ionic layer deposition method and their capacitive performance. Nanosystems: Physics, Chemistry, Mathematics, 2020, 11 (5), P. 573–578.
23. Lobinsky A.A., Kaneva M.V. Layer-by-layer synthesis of Zn-doped MnO2 nanocrystals as cathode materials for aqueous zinc-ion battery. Nanosystems: Physics, Chemistry, Mathematics, 2021, 12 (2), P. 182–187.
24. Lobinsky A.A., Tenevich M.I. Synthesis 2D nanocrystals of Co-doped manganese oxide as cathode materials of zinc-ion hybrid supercapacitor. Nanosystems: Physics, Chemistry, Mathematics, 2022, 13 (5), P. 525–529.
25. Lobinsky A.A., Kodintsev I.A., Tenevich M.I., Popkov V.I. A novel oxidation–reduction route for the morphology-controlled synthesis of manganese oxide nanocoating as highly effective material for pseudocapacitors. Coatings, 2023, 13 (2), 361.
26. Post J.E., Veblen D.R. Crystal structure determinations of synthetic sodium, magnesium, and potassium birnessite using TEM and the Rietveld method. American Mineralogist, 1990, 75.
27. Min S., Kim Y. Physicochemical characteristics of the birnessite and todorokite synthesized using various methods. Minerals, 2020, 10, P. 1–17.
28. Sabri M., King H.J., Gummow R.J., Malherbe F., Hocking R.K. The Oxidation of Peroxide by Disordered Metal Oxides: A Measurement of Thermodynamic Stability “By Proxy”. Chempluschem, 2018, 83, P. 620–629.
29. Post J.E., McKeown D.A., Heaney P.J. Raman spectroscopy study of manganese oxides: Layer structures. American Mineralogist, 2021, 106, P. 351–366.
30. Julien C., et al. Raman spectra of birnessite manganese dioxides. Solid State Ion, 2003, 159, P. 345–356.
Review
For citations:
Lobinsky A.A., Kaneva M.V., Bachina A.K., Tenevich M.I. SILD synthesis of porous manganese oxide nanocoatings as electroactive materials for pseudocapacitors. Nanosystems: Physics, Chemistry, Mathematics. 2023;14(5):554-559. https://doi.org/10.17586/2220-8054-2023-14-5-554-559
Views:
3
Email this article 