Исследование морфологических особенностей и термической стабильности регенерированной древесной целлюлозы из ее растворов в [BMIm]Cl
https://doi.org/10.17586/2220-8054-2025-16-3-364-373
Аннотация
Проведены исследования морфологических особенностей регенерированной древесной целлюлозы ЛС-0, полученной из ее растворов в [BMIm]Cl в диапазоне концентраций от 2% до 26%. Обнаружено, что при концентрациях ЛС-0 до 8% в [BMIm]Cl на термограммах наблюдается снижение ее термической стабильности с одновременным увеличением коксового остатка. В образцах регенерированной целлюлозы, полученной из растворов с содержанием ЛС-0 14% и более, на дифференциальных термогравиметрических кривых (DTG) наблюдаются два максимума. Это явление было объяснено присутствием двух фаз, образующихся в процессе растворения-регенерации. Методами ИК-спектроскопии и рентгеноструктурного анализа показано влияние [BMIm]Cl на морфологию регенерированной целлюлозы.
Ключевые слова
Об авторах
М. Г. Михалева
N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Россия
Россия
С. В. Усачев
N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Россия
Россия
А. С. Веденкин
N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences; Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Россия
Россия
М. И. Иким
N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Россия
Россия
Г. Г. Политенкова
N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Россия
Россия
С. М. Ломакин
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Россия
Россия
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Рецензия
Для цитирования:
Михалева М.Г., Усачев С.В., Веденкин А.С., Иким М.И., Политенкова Г.Г., Ломакин С.М. Исследование морфологических особенностей и термической стабильности регенерированной древесной целлюлозы из ее растворов в [BMIm]Cl. Наносистемы: физика, химия, математика. 2025;16(3):364-373. https://doi.org/10.17586/2220-8054-2025-16-3-364-373
For citation:
Mikhaleva M.G., Usachev S.V., Vedenkin A.S., Ikim M.I., Politenkova G.G., Lomakin S.M. Investigation of morphological features and thermal stability of regenerated wood cellulose from solutions in [BMIm]Cl. Nanosystems: Physics, Chemistry, Mathematics. 2025;16(3):364-373. https://doi.org/10.17586/2220-8054-2025-16-3-364-373
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