Synthesis of PbFe2.4X2.4Y2.4Ga2.4In2.4O19 high-entropy oxides with the magnetoplumbite structure
O. V. Zaitseva,
E. A. Trofimov,
V. E. Zhivulin,
A. Ostovari Mogaddam,
O. V. Samoilova,
K. S. Litvinyuk,
A. R. Zykova,
D. V. Mikhailov,
S. A. Gudkova,
D. A. Vinnik https://doi.org/10.17586/2220-8054-2023-14-3-354-362
Abstract
The purpose of this study is to obtain high-entropy oxides with the magnetoplumbite structure, in which the Pb cation is used as a divalent metal cation. The synthesis conditions were optimized, and a technique was developed to avoid the evaporation of lead oxide. For the first time, single-phase samples of high-entropy oxides with the magnetoplumbite structure were obtained, its chemical composition is reflected by the formula PbFe2.4X2.4Y2.4Ga2.4In2.4O19. The particle size of the high-entropy phase is about 100 nm, which makes it promising for a number of applications. The effect of preliminary grinding of the initial components on the results of synthesis was studied. A synthesis mechanism is proposed. The results pave the way to synthesis and study of the properties of a new large subgroup of high-entropy oxides with the magnetoplumbite structure, which expands the possibilities of controlling the properties of ceramic magnetic materials.
Keywords
Supporting agencies: This work was supported by the Russian Science Foundation (project No. 18-73- 10049).
About the Authors
O. V. Zaitseva
South Ural State University
Russian Federation
Russian Federation
Olga V. Zaitseva
Lenin Av., 76, Chelyabinsk, 454080
E. A. Trofimov
South Ural State University
Russian Federation
Russian Federation
Evgeny A. Trofimov
Lenin Av., 76, Chelyabinsk, 454080
V. E. Zhivulin
South Ural State University
Russian Federation
Russian Federation
Vladimir E. Zhivulin
Lenin Av., 76, Chelyabinsk, 454080
A. Ostovari Mogaddam
South Ural State University
Russian Federation
Russian Federation
Ahmad Ostovari Mogaddam
Lenin Av., 76, Chelyabinsk, 454080
O. V. Samoilova
South Ural State University
Russian Federation
Russian Federation
Olga V. Samoilova
Lenin Av., 76, Chelyabinsk, 454080
K. S. Litvinyuk
South Ural State University
Russian Federation
Russian Federation
Ksenia S. Litvinyuk
Lenin Av., 76, Chelyabinsk, 454080
A. R. Zykova
South Ural State University
Russian Federation
Russian Federation
Alena R. Zykova
Lenin Av., 76, Chelyabinsk, 454080
D. V. Mikhailov
South Ural State University
Russian Federation
Russian Federation
Dmitry V. Mikhailov
Lenin Av., 76, Chelyabinsk, 454080
S. A. Gudkova
South Ural State University
Russian Federation
Russian Federation
Svetlana A. Gudkova
Lenin Av., 76, Chelyabinsk, 454080
D. A. Vinnik
South Ural State University
Russian Federation
Russian Federation
Denis A. Vinnik
Lenin Av., 76, Chelyabinsk, 454080
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Review
For citations:
Zaitseva O.V., Trofimov E.A., Zhivulin V.E., Ostovari Mogaddam A., Samoilova O.V., Litvinyuk K.S., Zykova A.R., Mikhailov D.V., Gudkova S.A., Vinnik D.A. Synthesis of PbFe2.4X2.4Y2.4Ga2.4In2.4O19 high-entropy oxides with the magnetoplumbite structure. Nanosystems: Physics, Chemistry, Mathematics. 2023;14(3):354-362. https://doi.org/10.17586/2220-8054-2023-14-3-354-362
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