Kinetic of colloidal-chemical transformations during the decomposition of ammonia complexes of Zn(II) in alkaline solutions.
https://doi.org/10.17586/2220-8054-2024-15-4-498-509
Abstract
For the closed system (Σ): Zn2+–NH3,aq –NH3,gas, H+–OH−–N2,gas, experimental data on the change in the concentration of in the composition of the ammonia complex Zn(NH3)2+ 4 in solution, colloidal particles Zn(OH)2/ZnO in solution and growing film on the reactor walls are presented depending on the synthesis time, zinc concentration and synthesis temperature Ts in the range of 50 –99 ◦C. It has been established that up to 95 ◦C the ion-molecular growth of Zn(OH)2/ZnO clusters in solution (Σ) proceeds in a diffusion-controlled mode of homogeneous growth until reaching of their critical size. Further growth of ther critical clusters is followed by aggregation and coalescence of critical sized clusters into microcrystals with the formation of a film on a glass substrate of various morphologies. The solubility of such a film is determined by the size of critical clusters, which preserves in the growing polycrystal in the form of coherent scattering region (CSR). With an increase in the synthesis temperature to 99 ◦C, the aggregation mechanism is replaced by a faster diffusion-controlled attachment of Zn (II) ammonia complex to the end surface of the growing microcrystals simultaneously in colloid solution and in the film.
Supporting agencies: The work was carried out with the support of the State Program of Fundamental Scientific Research of the Russian Federation (project No. 124020600007-8)
About the Authors
M. A. Maksimova
ISSC UB RAS
Russian Federation
Russian Federation
Maria A. Maksimova
91, Pervomaiskaya str., 620108, Ekaterinburg
E. V. Polyakov
ISSC UB RAS
Russian Federation
Russian Federation
Evgeny V. Polyakov
91, Pervomaiskaya str., 620108, Ekaterinburg
I. V. Volkov
ISSC UB RAS
Russian Federation
Russian Federation
Ilya V. Volkov
91, Pervomaiskaya str., 620108, Ekaterinburg
A. P. Tyutyunnik
ISSC UB RAS
Russian Federation
Russian Federation
Aleksandr P. Tyutyunnik
91, Pervomaiskaya str., 620108, Ekaterinburg
A. A. Ioshin
ISSC UB RAS
Russian Federation
Russian Federation
Alexey A. Ioshin
91, Pervomaiskaya str., 620108, Ekaterinburg
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Review
For citations:
Maksimova M.A., Polyakov E.V., Volkov I.V., Tyutyunnik A.P., Ioshin A.A. Kinetic of colloidal-chemical transformations during the decomposition of ammonia complexes of Zn(II) in alkaline solutions. Nanosystems: Physics, Chemistry, Mathematics. 2024;15(4):498-509. https://doi.org/10.17586/2220-8054-2024-15-4-498-509
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