Composite sorbent based on Fe3O4 with Fe(N2H4)xCly for the removal of Chromium(VI) from wastewater.
D. P. Ordinartsev,
N. V. Pechishcheva,
S. Kh. Estemirova,
A. V. Kim,
E. V. Sterkhov,
S. A. Petrova,
G. A. Shilenko https://doi.org/10.17586/2220-8054-2024-15-4-510-519
Abstract
The paper presents a methodology for the synthesis of iron complex with hydrazine hydrate Fe(N2H4)xCly . The Fe(N2H4)xCly complex was investigated by X-ray phase analysis and scanning electron microscopy. Upon hydrolysis, the Fe(N2H4)xCly complex forms a composite sorbent, which is Fe3O4 in a shell of Fe(N2H4)xCly complex. The composite sorbent can be used to treat wastewater from Cr(VI) ions and is effective in the pH range of 2 to 12. Based on the adsorption and electrokinetic potential data, a conclusion about the nature of the terminal groups of the adsorbent was made, a scheme of the structure of its electrical double layer and the adsorption mechanism were proposed. Depending on the conditions, Cr(VI) can be adsorbed on the composite sorbent or reduced to Cr(III). The efficiency of the composite sorbent in the removal of Cr(VI) ions was tested on a sample of real wastewater.
Keywords
Supporting agencies: The work was carried out according to the state assignment of IMET UB RAS using equipment of Collaborative usage centre “Ural-M” and with the support of the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program), project No. 122080100074-1
About the Authors
D. P. Ordinartsev
Institute of Metallurgy of the Ural Branch of the Russian Academy of Science
Russian Federation
Russian Federation
Denis P. Ordinartsev
101, Amundsen street, Yekaterinburg, 620016
N. V. Pechishcheva
Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin
Russian Federation
Russian Federation
Nadezhda V. Pechishcheva
101, Amundsen street, Yekaterinburg, 620016; 19, Mira street, Yekaterinburg, 620002
S. Kh. Estemirova
Institute of Metallurgy of the Ural Branch of the Russian Academy of Science
Russian Federation
Russian Federation
Svetlana Kh. Estemirova
101, Amundsen street, Yekaterinburg, 620016
A. V. Kim
Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin
Russian Federation
Russian Federation
Angelina V. Kim
101, Amundsen street, Yekaterinburg, 620016; 19, Mira street, Yekaterinburg, 620002
E. V. Sterkhov
Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Evgenii V. Sterkhov
101, Amundsen street, Yekaterinburg, 620016
S. A. Petrova
Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Sofia A. Petrova
101, Amundsen street, Yekaterinburg, 620016
G. A. Shilenko
Ural Federal University named after the First President of Russia B. N. Yeltsin
Russian Federation
Russian Federation
Galina A. Shilenko
19, Mira street, Yekaterinburg, 620002
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Review
For citations:
Ordinartsev D.P., Pechishcheva N.V., Estemirova S.Kh., Kim A.V., Sterkhov E.V., Petrova S.A., Shilenko G.A. Composite sorbent based on Fe3O4 with Fe(N2H4)xCly for the removal of Chromium(VI) from wastewater. Nanosystems: Physics, Chemistry, Mathematics. 2024;15(4):510-519. https://doi.org/10.17586/2220-8054-2024-15-4-510-519
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