Ultrasonic-assisted hydrothermal synthesis of nanoscale double ceric phosphates
T. O. Kozlova,
E. D. Sheichenko,
D. N. Vasilyeva,
D. A. Kozlov,
I. V. Kolesnik,
I. V. Tronev,
M. A. Teplonogova,
A. E. Baranchikov,
V. K. Ivanov https://doi.org/10.17586/2220-8054-2024-15-2-215-223
Abstract
The combination of ultrasonic exposure on ceric phosphate gels with subsequent hydrothermal-microwave treatment resulted in the formation of nanoscale NH4Ce2(PO4)3 or KCe2(PO4)3 phases. The sun protection factor (SPF) and protection factor against UV-A radiation (UVAPF) values for double ceric phosphates with the smallest crystallite sizes exceeded 4 and 3.5, respectively, which is much higher than the values for samples consisting of larger particles. These results are superior to previously published values for similar ceric compounds, and thus show promise for their application in sunscreens.
Supporting agencies: This work was supported by Russian Science Foundation (Grant no. 23-73-10088, https://rscf.ru/en/project/23-73-10088/) using the equipment of the JRC PMR IGIC RAS.
About the Authors
T. O. Kozlova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Taisiya O. Kozlova.
Leninsky prospect, 31, Moscow, 119991
E. D. Sheichenko
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; National Research University Higher School of Economics
Russian Federation
Russian Federation
Ekaterina D. Sheichenko.
Leninsky prospect, 31, Moscow, 119991; Moscow, Myasnitskaya str., 20, 101000
D. N. Vasilyeva
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; National Research University Higher School of Economics
Russian Federation
Russian Federation
Darya N. Vasilyeva.
Leninsky prospect, 31, Moscow, 119991; Moscow, Myasnitskaya str., 20, 101000
D. A. Kozlov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Daniil A. Kozlov.
Leninsky prospect, 31, Moscow, 119991
I. V. Kolesnik
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Lomonosov Moscow State University
Russian Federation
Russian Federation
Irina V. Kolesnik.
Leninsky prospect, 31, Moscow, 119991; Leninskie Gory 1, Moscow, 119991
I. V. Tronev
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; National Research University Higher School of Economics
Russian Federation
Russian Federation
Ilya V. Tronev.
Leninsky prospect, 31, Moscow, 119991; Moscow, Myasnitskaya str., 20, 101000
M. A. Teplonogova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Maria A. Teplonogova.
Leninsky prospect, 31, Moscow, 119991
A. E. Baranchikov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Alexander E. Baranchikov.
Leninsky prospect, 31, Moscow, 119991
V. K. Ivanov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Vladimir K. Ivanov.
Leninsky prospect, 31, Moscow, 119991
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For citations:
Kozlova T.O., Sheichenko E.D., Vasilyeva D.N., Kozlov D.A., Kolesnik I.V., Tronev I.V., Teplonogova M.A., Baranchikov A.E., Ivanov V.K. Ultrasonic-assisted hydrothermal synthesis of nanoscale double ceric phosphates. Nanosystems: Physics, Chemistry, Mathematics. 2024;15(2):215-223. https://doi.org/10.17586/2220-8054-2024-15-2-215-223
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