Гидротермальный синтез нанокристаллических двойных ортофосфатов церия(IV) с использованием ультразвукового воздействия

Сочетание ультразвукового воздействия на церийфосфатные гели с их последующей гидротермально-микроволновой обработкой привело к образованию наноразмерных фаз NH₄Ce₂(PO₄)₃ или KCe₂(PO₄)₃. Солнцезащитный фактор (SPF) и фактор защиты от УФ-А-излучения (UVAPF) для двойных ортофосфатов церия(IV) с наименьшими размерами частиц превысили значения 4 и 3,5 соответственно, что оказалось значительно выше соответствующих значений для образцов, состоящих из более крупных частиц. Полученные данные превосходят ранее опубликованные значения для аналогичных соединений церия и, таким образом, указывают на перспективность применения полученных соединений в солнцезащитных средствах.

1. Gallagher R.P., Lee T.K. Adverse Effects of Ultraviolet Radiation: A Brief Review. Prog. Biophys. Mol. Biol., 2006, 92, P. 119–131.

2. González S., Fernández-Lorente M., Gilaberte-Calzada Y. The Latest on Skin Photoprotection. Clin. Dermatol., 2008, 26, P. 614–626.

3. Wang S.Q., Balagula Y., Osterwalder U. Photoprotection: A Review of the Current and Future Technologies. Dermatol. Ther., 2010, 23, P. 31–47.

4. Egambaram O.P., Kesavan Pillai S., Ray S.S. Materials Science Challenges in Skin UV Protection: A Review. Photochem. Photobiol., 2020, 96, P. 779–797.

5. Schneider S.L., Lim H.W. A Review of Inorganic UV Filters Zinc Oxide and Titanium Dioxide. Photodermatol. Photoimmunol. Photomed., 2019, 35, P. 442–446.

6. Onoda H., Iwashita M. Synthesis of Novel White Pigments by Shaking Cerium Compounds with Phosphoric Acid. Emergent Mater., 2023, 6, P. 1089–1095.

7. Onoda H., Tanaka R. Synthesis of Cerium Phosphate White Pigments from Cerium Carbonate for Cosmetics. J. Mater. Res. Technol., 2019, 8, P. 5524–5528.

8. Achary S.N., Bevara S., Tyagi A.K. Recent Progress on Synthesis and Structural Aspects of Rare-Earth Phosphates. Coord. Chem. Rev., 2017, 340, P. 266–297.

9. Sato T., Li R., Sato C., Yin S. Synthesis and Photochemical Properties of Micaceous Cerium Phosphates. Phosphorus Res. Bull., 2007, 21, P. 44–47.

10. Sato T., Sato C., Yin S. Optimization of Hydrothermal Synthesis of Plate-Like Hydrated Cerium Phosphates and Their Photochemical Properties. Phosphorus Res. Bull., 2008, 22, P. 17–21.

11. Sato T., Yin S. Morphology Control of Cerium Phosphates for UV-Shielding Application. Phosphorus Res. Bull., 2010, 24, P. 43–48.

12. Kozlova T.O., Popov A.L., Kolesnik I. V., Kolmanovich D.D., Baranchikov A.E., Shcherbakov A.B., Ivanov V.K. Amorphous and Crystalline Cerium(IV) Phosphates: Biocompatible ROS-Scavenging Sunscreens. J. Mater. Chem. B, 2022, 10, P. 1775–1785.

13. Nazaraly M., Quarton M., Wallez G., Chanéac C., Ribot F., Jolivet J.P. Ce(H2O)(PO4)3/2(H3O)1/2(H2O)1/2, a Second Entry in the Structural Chemistry of Cerium(IV) Phosphates. Solid State Sci., 2007, 9, P. 672–677.

14. Nazaraly M., Chanéac C., Ribot F., Wallez G., Quarton M., Jolivet J.P. A New Story in the Structural Chemistry of Cerium(IV) Phosphate. J. Phys. Chem. Solids, 2007, 68, P. 795–798.

15. Nazaraly M., Wallez G., Chanéac C., Tronc E., Ribot F., Quarton M., Jolivet J.P. Synthesis and Characterization of CeIV(PO4)(HPO4)0.5(H2O)0.5. J. Phys. Chem. Solids, 2006, 67, P. 1075–1078.

16. Brandel V., Clavier N., Dacheux N. Synthesis and Characterization of Uranium (IV) Phosphate-Hydrogenphosphate Hydrate and Cerium (IV) Phosphate-Hydrogenphosphate Hydrate. J. Solid State Chem., 2005, 178, P. 1054–1063.

17. Shekunova T.O., Istomin S.Y., Mironov A. V., Baranchikov A.E., Yapryntsev A.D., Galstyan A.A., Simonenko N.P., Gippius A.A., Zhurenko S.V., Shatalova T.B., Skogareva L.S., Ivanov V.K. Crystallization Pathways of Cerium(IV) Phosphates Under Hydrothermal Conditions: A Search for New Phases with a Tunnel Structure. Eur. J. Inorg. Chem., 2019, 2019, P. 3242–3248.

18. Kozlova T.O., Mironov A.V., Istomin S.Y., Birichevskaya K.V., Gippius A.A., Zhurenko S.V., Shatalova T.B., Baranchikov A.E., Ivanov V.K. Meet the Cerium(IV) Phosphate Sisters: CeIV (OH)PO4 and CeIV O(PO4)2. Chem. – A Eur. J., 2020, 26, P. 12188–12193.

19. Kozlova T.O., Vasilyeva D.N., Kozlov D.A., Teplonogova M.A., Baranchikov A.E., Simonenko N.P., Ivanov V.K. Synthesis and Thermal Behavior of KCe2(PO4)3, a New Full-Member in the AI MIV (PO4)3 Family. Nanosyst. Phys. Chem. Math., 2023, 14, P. 112–119.

20. Serpone N., Dondi D., Albini A. Inorganic and Organic UV Filters: Their Role and Efficacy in Sunscreens and Suncare Products. Inorganica Chim. Acta, 2007, 360, P. 794–802.

21. Ngoc T., Moon C., Park L. Recent Trends of Sunscreen Cosmetic: An Update Review. Cosmetics, 2019, 6, 64.

22. Geoffrey K., Mwangi A.N., Maru S.M. Sunscreen Products: Rationale for Use, Formulation Development and Regulatory Considerations. Saudi Pharm. J., 2019, 27, P. 1009–1018.

23. Tronev I.V., Sheichenko E.D., Razvorotneva L.S., Trufanova E.A., Minakova P.V., Kozlova T.O., Baranchikov A.E., Ivanov V.K. Microwave-Assisted Hydrothermal Synthesis of Ceric-Ammonium Phosphates (NH4)2Ce(PO4)2·H2O and NH4Ce2(PO4)3. Russ. J. Inorg. Chem., 2023, 68, P. 263–269.

24. Yapryntsev A.D., Baranchikov A.E., Ivanov V.K., Tret’yakov Y.D. Chromium(III) Oxyhydroxide Synthesis under Intense Sonication. Dokl. Chem., 2012, 446, P. 180–182.

25. Yapryntsev A.D., Baranchikov A.E., Gubanova N.N., Ivanov V.K., Tret’yakov Y.D. Synthesis of Nanocrystalline ZrO2 with Tailored Phase Composition and Microstructure under High-Power Sonication. Inorg. Mater., 2012, 48, P. 494–499.

26. Yang G., Lin W., Lai H., Tong J., Lei J., Yuan M., Zhang Y., Cui C. Understanding the Relationship between Particle Size and Ultrasonic Treatment during the Synthesis of Metal Nanoparticles. Ultrason. Sonochem., 2021, 73, 105497.

27. Kozlova T.O., Baranchikov A.E., Birichevskaya K.V., Kozlov D.A., Simonenko N.P., Gavrikov A.V., Teplonogova M.A., Ivanov V.K. On the Thermal Decomposition of Cerium(IV) Hydrogen Phosphate Ce(PO4)(HPO4)0.5(H2O)0.5. Russ. J. Inorg. Chem., 2021, 66, P. 1624–1632.

28. Baranchikov A.E., Polezhaeva O.S., Ivanov V.K., Tretyakov Y.D. Lattice Expansion and Oxygen Non-Stoichiometry of Nanocrystalline Ceria. CrystEngComm, 2010, 12, P. 3531–3533.

29. Shekunova T.O., Baranchikov A.E., Ivanova O.S., Skogareva L.S., Simonenko N.P., Karavanova Y.A., Lebedev V.A., Borilo L.P., Ivanov V.K. Cerous Phosphate Gels: Synthesis, Thermal Decomposition and Hydrothermal Crystallization Paths. J. Non. Cryst. Solids, 2016, 447, P. 183–189.

30. Kozlova T.O., Vasil’eva D.N., Kozlov D.A., Teplonogova M.A., Birichevskaya K.V., Baranchikov A.E., Gavrikov A.V., Ivanov V.K. On the Chemical Stability of CeIV (PO4)(HPO4)0.5(H2O)0.5 in Alkaline Media. Russ. J. Inorg. Chem., 2022, 67, P. 1901–1907.

31. Skogareva L.S., Shekunova T.O., Baranchikov A.E., Yapryntsev A.D., Sadovnikov A.A., Ryumin M.A., Minaeva N.A., Ivanov V.K. Synthesis of Cerium Orthophosphates with Monazite and Rhabdophane Structure from Phosphoric Acid Solutions in the Presence of Hydrogen Peroxide. Russ. J. Inorg. Chem., 2016, 61, P. 1219–1224.

32. Clavier N., Mesbah A., Szenknect S., Dacheux N. Monazite, Rhabdophane, Xenotime & Churchite: Vibrational Spectroscopy of Gadolinium Phosphate Polymorphs. Spectrochim. Acta – Part A Mol. Biomol. Spectrosc., 2018, 205, P. 85–94.

33. Petit S., Righi D., Madejová J. Infrared Spectroscopy of NH+-Bearing and Saturated Clay Minerals: A Review of the Study of Layer Charge. Appl. Clay Sci., 2006, 34, P. 22–30.

34. Petit S., Righi D., Madejová J., Decarreau A. Interpretation of the Infrared NH4+ Spectrum of the NH+-Clays: Application to the Evaluation of the Layer Charge. Clay Miner., 1999, 34, P. 543–549.

35. Kloprogge J.T., Broekmans M., Duong L.V., Martens W.N., Hickey L., Frost R.L. Low Temperature Synthesis and Characterisation of Lecontite, (NH4)Na(SO4)2H2O. J. Mater. Sci., 2006, 41, P. 3535–3539.

36. Kopitsa G.P., Baranchikov A.E., Ivanova O.S., Yapryntsev A.D., Grigoriev S. V, Pranzas P.K., Ivanov V.K. Effect of High Intensity Ultrasound on the Mesostructure of Hydrated Zirconia. J. Phys. Conf. Ser., 2012, 340, 012057.

37. Ivanov V.K., Kopitsa G.P., Sharikov F.Y., Baranchikov A.Y., Shaporev A.S., Grigoriev S.V., Pranzas P.K. Ultrasound-Induced Changes in Mesostructure of Amorphous Iron (III) Hydroxide Xerogels: A Small-Angle Neutron Scattering Study. Phys. Rev. B, 2010, 81, 174201.

38. Kuznetsova V.A., Almjasheva O.V., Gusarov V.V. Influence of Microwave and Ultrasonic Treatment on the Formation of CoFe2O4 under Hydrothermal Conditions. Glas. Phys. Chem., 2009, 35, P. 205–209.

39. Rezaei P., Rezaei M., Meshkani F. Ultrasound-Assisted Hydrothermal Method for the Preparation of the M-Fe2O3−CuO (M: Mn, Ag, Co) Mixed Oxides Nanocatalysts for Low-Temperature CO Oxidation. Ultrason. Sonochem., 2019, 57, P. 212–222.

40. Charghand M., Haghighi M., Saedy S., Aghamohammadi S. Efficient Hydrothermal Synthesis of Nanostructured SAPO-34 Using Ultrasound Energy: Physicochemical Characterization and Catalytic Performance toward Methanol Conversion to Light Olefins. Adv. Powder Technol., 2014, 25, P. 1728–1736.

41. Kolesnik I.V., Shcherbakov A.B., Kozlova T.O., Kozlov D.A., Ivanov V.K. Comparative Analysis of Sun Protection Characteristics of Nanocrystalline Cerium Dioxide. Russ. J. Inorg. Chem., 2020, 65, P. 960–966.

42. Goh E.G., Xu X., McCormick P.G. Effect of Particle Size on the UV Absorbance of Zinc Oxide Nanoparticles. Scr. Mater., 2014, 78–79, P. 49–52.

43. Shi W., Lin Y., Zhang S., Tian R., Liang R., Wei M., Evans D.G., Duan X. Study on UV-Shielding Mechanism of Layered Double Hydroxide Materials. Phys. Chem. Chem. Phys., 2013, 15, 18217.

44. Kim J.H., Choi J., Choi S., Kim W., Lee S. Study on the Dependence of Sun Protection Factor on Particle Size Distribution of Mica Using Gravitational Field-Flow Fractionation. Bull. Korean Chem. Soc., 2020, 41, P. 66–72.

45. Silva M.R.F., Alves M.F.R.P., Cunha J.P.G.Q., Costa J.L., Silva C.A., Fernandes M.H.V., Vilarinho P.M., Ferreira P. Nanostructured Transparent Solutions for UV-Shielding: Recent Developments and Future Challenges. Mater. Today Phys., 2023, 35, 101131.