Синтез феррита магния методом горения глицин-нитратного геля: влияние реагентов на гель-прекурсор и микроструктуру нанопорошков
https://doi.org/10.17586/2220-8054-2024-15-2-224-232
Аннотация
В данной работе исследовано влияние исходных реагентов на фазовый состав и морфологию феррита магния, полученного сжиганием глицин-нитратного геля. Локальное окружение ионов железа в геле-прекурсоре детально изучено методами ИК-Фурье, XANES- и EXAFS-спектроскопии. Установлено, что в геле-прекурсоре, полученном растворением металлов (Mg, Fe) в разбавленной азотной кислоте, образуются биядерные комплексы Fe(III), тогда как в аналогичном геле-прекурсоре, полученном из кристаллогидратов нитратов соответствующих металлов преобладают трехъядерные комплексы Fe(III). Горение геля, состоящего из биядерных комплексов Fe(III), приводит к образованию нанокристаллического порошка феррита магния, характеризующегося унимодальным распределением частиц по размерам.
Об авторах
М. Н. Смирнова
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
Г. Е. Никифорова
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
О. Н. Кондратьева
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Россия
Россия
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Рецензия
Для цитирования:
Смирнова М.Н., Никифорова Г.Е., Кондратьева О.Н. Синтез феррита магния методом горения глицин-нитратного геля: влияние реагентов на гель-прекурсор и микроструктуру нанопорошков. Наносистемы: физика, химия, математика. 2024;15(2):224-232. https://doi.org/10.17586/2220-8054-2024-15-2-224-232
For citation:
Smirnova M.N., Nikiforova G.E., Kondrat’eva O.N. Synthesis of magnesium ferrite by combustion of glycine-nitrate gel: the influence of reagents on the gel-precursor and the microstructure of nanopowders. Nanosystems: Physics, Chemistry, Mathematics. 2024;15(2):224-232. https://doi.org/10.17586/2220-8054-2024-15-2-224-232
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