Никель-медные сплавные катализаторы гидроконверсии фурфурола: влияние состава и физико-химических характеристик на распределение продуктов реакции в различных режимах
https://doi.org/10.17586/2220-8054-2025-16-1-105-115
Аннотация
Сплавные никель-медьсодержащие катализаторы с различным содержанием оксида никеля были приготовлены и протестированы в процессе гидроконверсии фурфурола до 2-метилфурана и фурфурилового спирта. Выбран наиболее активный катализатор (7Ni19Cu61Fe13Al), а также подобраны условия реакции, обеспечивающие высокий выход 2-метилфурана (81 мас. %) при 100 % конверсии фурфурола в реакторе периодического действия: Т = 200 °С, Р(Н2) = 5,0 МПа, время реакции 4 ч. Выбранный катализатор исследован комплексом физико-химических методов, определены его фазовый и поверхностный составы, морфология активного компонента, выявлена причина дезактивации катализатора в ходе реакции, возникающая за счет необратимой сорбции реагентов и продуктов реакции, а также продуктов их взаимодействия на поверхности катализатора. Показана возможность получения 2-метилфурана в присутствии катализатора 7Ni19Cu61Fe13Al с селективностью 70 % при 87 % конверсии фурфурола в проточном реакторе без растворителя при LHSV = 6 ч-1, 200 °С, давлении водорода 5 МПа.
Об авторах
А. А. Сумина
Federal Research Center Boreskov Institute of Catalysis SB RAS
Россия
Россия
С. А. Селищева
Federal Research Center Boreskov Institute of Catalysis SB RAS
Россия
Россия
О. А. Булавченко
Federal Research Center Boreskov Institute of Catalysis SB RAS
Россия
Россия
В. А. Яковлев
Federal Research Center Boreskov Institute of Catalysis SB RAS
Россия
Россия
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Рецензия
Для цитирования:
Сумина А.А., Селищева С.А., Булавченко О.А., Яковлев В.А. Никель-медные сплавные катализаторы гидроконверсии фурфурола: влияние состава и физико-химических характеристик на распределение продуктов реакции в различных режимах. Наносистемы: физика, химия, математика. 2025;16(1):105-115. https://doi.org/10.17586/2220-8054-2025-16-1-105-115
For citation:
Sumina A.A., Selishcheva S.A., Bulavchenko O.A., Yakovle V.A. Nickel-copper-containing alloy catalysts for furfural hydroconversion: the influence of composition and physicochemical features on the distribution of reaction products in various modes. Nanosystems: Physics, Chemistry, Mathematics. 2025;16(1):105-115. https://doi.org/10.17586/2220-8054-2025-16-1-105-115
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