Магнитные и фотокаталитические свойства наночастиц BiFeO₃, формирующихся при термообработке соосаждённых в микрореакторе с закрученными потоками гидроксидов

   В работе для получения BiFeO₃ использовалось осаждение гидроксидов в микрореакторе с закручивающимися потоками с последующей термообработкой соосажденных гидроксидов висмута и железа. Изучение процесса образования нанокристаллического ортоферрита висмута проводилось с использованием комплекса методов: EDXMA, TEM, XRD, ⁵⁷Fe Mössbauer spectroscopy, DRS и др. Были определены фотокаталитическая активность и магнитные характеристики материала. Показано, что при термообработке осадков гидроксидов в течение 1 минуты при температуре 530 °C формируются нанокристаллы BiFeO₃ со средним размером кристаллитов 14 ± 7 нм. Установлено, что полученный нанопорошок BiFeO₃ представлен агломератами отдельных наночастиц. Значения намагниченности насыщения и остаточной намагниченности этих наночастиц ортоферрита висмута равны 2.31 и 0.48 emu/g, соответственно. По результатам DRS установлено, что энергия запрещенной зоны для образцов, прокаленных в 530 °C, 515 °C, и 500 °C составила 1,82 эВ, 1,86 эВ и 1,91 эВ соответственно,, что обеспечивает сильное поглощение видимого света образцами. Более высокую фотокаталитическую активность проявил образец в рентгеноаморфном состоянии по сравнению с нанокристаллическим BiFeO₃ в процессе фентоноподобного обесцвечивания метилового фиолетового под действием видимого света с константами скорости реакции псевдопервого порядка 0.0256 мин^-1 и 0.0072 мин^-1, соответственно.

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