Синтез и исследование наночастиц и наноструктур сульфида никеля для применения в устройствах накопления энергии

   Наноструктуры сульфида никеля (NiS) синтезированы простым и дешевым методом горячей инъекции (МГИ). Детально исследовано влияние концентрации серы на композиционные, морфологические, оптические и структурные свойства наночастиц NiS. Рентгеновская дифрактограмма подтверждает образование наночастиц NiS без каких-либо примесей. Спектры комбинационного рассеяния света показывают наличие активных мод NiS в синтезированном материале, полученном при различной концентрации серы. Электрохимические характеристики синтезированного порошка NiS оценены методами циклической вольтамперометрии, гальваностатического заряда-разряда и электрохимической импедансной спектроскопии в электролите КОН. Удельная емкость порошкового электрода NiS была измерена трехэлектродным методом и подтверждает максимальное значение 315.8 Ф/г при скорости сканирования 5 мВ∙с^-1. Расчетное значение плотности энергии и плотности мощности порошкового электрода NiS составляет 3.324 Вт∙ч∙кг^-1 и 199 Вт∙кг^-1 соответственно при меньшей плотности тока. Настоящее исследование предлагает простой и недорогой метод – МГИ, позволяющий контролировать структурные, оптические и морфологические свойства сульфида никеля, и который имеет большой потенциал для синтеза сульфидов других металлов.

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