The role and effect of CO₂ flow rate on the structure formation of ultrahigh porous activated carbon from H₃PO₄-impregnated waste cotton used as supercapacitor electrode material

Ultrahigh porosity activated carbon (AC) was made from H3PO4-impregnated waste cotton precursor by carbonization in Ar and physical activation in variable CO2 flow rate with ultrahigh heating rate. The presence of CO2 in the activation plays an important role in the formation of the porous structure of AC. The obtained AC had outstanding physical and electrochemical properties. The specific surface area and micropore volume of AC reached 4800.7 m2 /g and 2.499 cm3 /g, respectively. The pore size distribution was mainly in the microporous region. The electrochemical double-layer capacitors (EDLCs) with AC-based active electrode and an electrolyte solution of 1 M 1,1-dimethylpyrrolidinium tetrafluoroborate in acetonitrile were fabricated. The specific capacitance of electrode material degraded less than 10 % with the highest value of 105.7 F/g at 0.05 A/g as the specific current varied from 0.05 A/g – 15 A/g. After 8000 charge-discharge cycles at 1 A/g, the specific capacitance of the AC-base electrode material fabricated at CO2 flow rate greater than 200 ml/min degraded less than 15 % with the highest value of 101.2 F/g. The optimal CO2 flow rate for fabricating waste cotton-based AC is 200 ml/min. 

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