Pt(0) microscrolls obtained on nickel surface by galvanic replacement reaction in H2PtCl6 solution as the basis for creating new SERS substrates
https://doi.org/10.17586/2220-8054-2022-13-5-509-513
Abstract
The paper explores the morphology features of Pt(0) nanolayers obtained on the surface of chemically polished nickel as a result of the galvanic replacement reaction using H2PtCl6 solution. In a series of samples synthesized at a treatment time of 1-60 minutes, it is shown that the nanolayers consist of Pt(0) nanocrystals 5-10 nm in size, which form a continuous porous layer with a thickness depending on the treatment time in solution. For example, it is about 80 nm and 120 nm for samples obtained after 3 minutes and 20 minutes, respectively. Moreover, on the outer side of the nanolayer with respect to the substrate, these nanocrystals form arrays of pointed agglomerates directed along the normal to the surface. After drying in air, the Pt(0) nanolayer cracks and partially folded microscrolls form on the nickel surface, the number of which is the largest for the samples obtained with a longer treatment time. The features of the practical application of these samples as SERS substrates are studied using the Raman spectra of Rodamin 6G as an example. It is shown that the amplification factor is about 105-106 using 532 nm laser excitation.
About the Authors
M. V. Kaneva
Saint Petersburg State University
Russian Federation
Russian Federation
E. V. Borisov
Saint Petersburg State University
Russian Federation
Russian Federation
V. P. Tolstoy
Saint Petersburg State University
Russian Federation
Russian Federation
References
1. Gong T., Das C.M., Yin M.-J., Lv T.-R., Singh N.M., Soehartono A.M., Singh G., An Q.-F., Yong K.-T. Development of SERS tags for human diseases screening and detection. Coordination Chemistry Reviews, 2022, 470, P. 214711.
2. Yin Z., Li Y., Xu J., Qian Z.F., Xiong K. Recent advances of perovskite materials for surface enhanced Raman scattering and their applications. Materials Today Physics, 2022, 27, P. 100815.
3. Liu C., Xu D., Dong X., Huang Q. A review: Research progress of SERS-based sensors for agricultural applications. Trends in Food Science and Technology, 2022, 128, P. 90-101.
4. Povolotckaia A., Pankin D., Petrov Y., Vasileva A., Kolesnikov I., Sarau G., Christiansen S., Leuchs G., Manshina A. Plasmonic carbon nanohybrids from laser-induced deposition: controlled synthesis and SERS properties. Journal of Materials Science, 2019, 54(11), P. 8177-8186.
5. Samodelova M.V., Kapitanova O.O., Evdokimov P.V., Eremina O.E., Goodilin E.A., Veselova I.A. Plasmonic features of free-standing chitosan nanocomposite film with silver and graphene oxide for SERS applications. Nanotechnology, 2022, 33(33), P. 335501.
6. Eremina O.E., Sergeeva E.A., Ferree M.V., Shekhovtsova T.N., Goodilin E.A., Veselova I.A. Dual-purpose SERS sensor for selective determination of polycyclic aromatic compounds via electron donor-acceptor traps. ACS Sensors, 2021, 6(3), P. 1057-1066.
7. Semenova A.A., Veselova I.A., Brazhe N.A., Shevelkov A.V., Goodilin E.A. Soft chemistry of pure silver as unique plasmonic metal of the Periodic Table of Elements. Pure and Applied Chemistry, 2020, 92(7), P. 1007-1028.
8. Eremina O.E., Kapitanova O.O., Goodilin E.A., Veselova I.A. Silver-chitosan nanocomposite as a plasmonic platform for SERS sensing of polyaromatic sulfur heterocycles in oil fuel. Nanotechnology, 2020, 31(22), P. 225503.
9. Ye J., Jiang J., Zhao Y.S., Yao J. Nano- and microstructured gold tubes for surface-enhanced Raman scattering by vapor-induced strain of thin films. Journal of Materials Chemistry A, 2012, 22, P. 19202.
10. Wang X., Wang Q., Chai Z., Mao G., Liu H., Ren X. Gold nanoparticle-induced diameter reduction and enhanced Raman shift in self-rolled-up InGaAs/GaAs microtubes. Nanophotonics and Micro/Nano Optics III, 2016, 10027, P. 100270N.
11. Pal U., Castillo Lo´pez D. N., Carcan˜o-Montiel M. G., Lo´pez-Reyes L., D´ıaz-Nun˜ez P., Pen˜a-Rodr´ıguez O. Nanoparticle-assembled gold microtubes built on fungi templates for SERS-based molecular sensing. ACS Applied Nano Materials, 2019, 2(4), P. 2533-2541.
12. Perales-Rondon J.V., Colina A., Gonza´lez M.C., Escarpa A., Roughened silver microtubes for reproducible and quantitative SERS using a template-assisted electrosynthesis approach. Applied Materials Today, 2020, 20, P. 100710.
13. Zhang Y., Han D., Du D. Rolled-up Ag-SiOx hyperbolic metamaterials for surface-enhanced Raman scattering. Plasmonics, 2015, 10, P. 949-954.
14. Zhang Z., Tian Z., Mei Y., Di Z. Shaping and structuring 2D materials via kirigami and origami. Materials Science and Engineering: R:Reports, 2021, 145, P. 100621.
15. Khalisov M.M., Lebedev V.A., Poluboyarinov A.S., Garshev A.V., Khrapova E.K., Krasilin A.A., Ankudinov A.V. Young’s modulus of phyllosilicate nanoscrolls measured by the AFM and by the in-situ TEM indentation. Nanosystems: physics, chemistry, mathematics, 2021, 12(1), P. 118-127.
16. Levin A., Khrapova E., Kozlov D., Krasilin A., Gusarov V. Structure refinement, microstrains and crystallite sizes of Mg-Ni-phyllosilicate nanoscroll powders. Journal of Applied Crystallography, 2022, 55(3), P. 484-502.
17. Krasilin A.A., Gusarov V.V. Energy model of bilayer nanoplate scrolling: Formation of chrysotile nanoscroll.Russian Journal of General Chemistry, 2015, 85, P. 2238-2241.
18. Tolstoy V.P., Gulina L.B. New way of As2S3 microtubules preparation by roll up thin films synthesized at the air-solution interface. Journal of Nano- and Electronic Physics, 2013, 5(1), P. 01003.
19. Gulina L.B., Tolstoy V.P., Solovev A.A., Gurenko V.E., Huang G., Mei Y. Gas-solution interface technique as a simple method to produce inorganic microtubes with scroll morphology. Progress in Natural Science: Materials International, 2020, 30(3), P. 279-288.
20. Kaneva M.V., Tolstoy V.P. The “rolling up” effect of platinum layer obtained on nickel surface by interaction with solution of H2PtCl6 and its electrocatalytic properties in hydrogen evolution reaction during water electrolysis in alkaline medium. Nanosystems: Physics, Chemistry, Mathematics, 2021, 12(5), P. 630-633.
21. Yang C.-P., Fang S.-U., Tsai H.-Y., Chen J.-W., Liu Y.-C. Newly prepared surface-enhanced Raman scattering-active substrates for sensing pesticides. Journal of Electroanalytical Chemistry, 2020, 861, P. 113965.
22. Navarro-Segura M.E., Rivera-Rangel R.D., Arizmendi-Morquecho A., Lo´pez I., Alvarez-Quintana J., Sanchez-Dominguez M. Ultra-high Sensitivity Surface-Enhanced Raman Spectroscopy (SERS) Substrates Based on Au Nanostructured Hollow Octahedra. Applied Materials Today, 2022, 29, P. 101598.
23. Jiang Z., Li C., Liu Y., Jing Q., Liang A. A sensitive Galvanic replacement reaction-SERS method for Au(III) with Victoria blue B molecular probes in silver nanosol substrate. Sensors and Actuators, B: Chemical, 2017, 251, P. 404-409. x
24. Kaneva M.V., Reveguk A.A., Tolstoy V.P. SILD-preparation of nanostructured Ru0 -RuO2·nH2O thin films: Effect of deposition cycles on electrocatalytic properties.
25. Kirubha E., Palanisamy P.K. Green synthesis, characterization of Au-Ag core-shell nanoparticles using gripe water and their applications in nonlinear optics and surface enhanced Raman studies. Advances in Natural Sciences: Nanoscience and Nanotechnology, 2014, 5, P. 045006.
26. Bigall N.C., Ha¨rtling T., Klose M., Simon P., Eng L.M., Eychmu¨ller A. Monodisperse platinum nanospheres with adjustable diameters from 10 to 100 nm: synthesis and distinct optical properties. Nano Letters, 2008, 8, P. 4588-4592.
Review
For citations:
Kaneva M.V., Borisov E.V., Tolstoy V.P. Pt(0) microscrolls obtained on nickel surface by galvanic replacement reaction in H2PtCl6 solution as the basis for creating new SERS substrates. Nanosystems: Physics, Chemistry, Mathematics. 2022;13(5):509-513. https://doi.org/10.17586/2220-8054-2022-13-5-509-513
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