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Planar perovskite solar cells with La2NiMnO6 buffer layer

https://doi.org/10.17586/2220-8054-2023-14-5-584-589

Abstract

Thin films of La2NiMnO6 (LNMO) double perovskite oxide were first used as buffer layers in planar perovskite solar cells (PSCs) with the architecture of glass/FTO/LNMO/CH3NH3PbI3/Spiro-MeOTAD/Au. All PSCs were fabricated under ambient conditions and their photovoltaic parameters were measured under standard illumination (AM1.5G, 1000 W/m2). Power conversion efficiency (PCE) values (10 – 11 %) for the PSCs developed were comparable with those obtained for conventional PSCs with compact TiO2 (cTiO2) layer, but the stability of PSCs with LNMO buffer layer was significantly higher than for cTiO2-based PSCs.

About the Authors

S. S. Kozlov
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Russian Federation

Sergey S. Kozlov

Kosygin St., 4, Moscow, 119334



A. B. Nikolskaia
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Russian Federation

Anna B. Nikolskaia

Kosygin St., 4, Moscow, 119334



O. K. Karyagina
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Russian Federation

Olga K. Karyagina

Kosygin St., 4, Moscow, 119334



E. K. Kosareva
N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Science
Russian Federation

Ekaterina K. Kosareva

Kosygin St., 4, Moscow, 119991



O V. Alexeeva
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Russian Federation

Olga V. Alexeeva

Kosygin St., 4, Moscow, 119334



V. I. Petrova
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Russian Federation

Vasilisa I. Petrova

Kosygin St., 4, Moscow, 119334



O. V. Almjasheva
St. Petersburg State Electrotechnical University “LETI”; Ioffe Physical-Technical Institute, Russian Academy of Sciences
Russian Federation

Oksana V. Almjasheva

Professora Popova St., 5, St. Petersburg, 197376

Politekhnicheskaya St., 26, St. Petersburg, 194021



O. I. Shevaleevskiy
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
Russian Federation

Oleg I. Shevaleevskiy

Kosygin St., 4, Moscow, 119334



References

1. Kumar N.S., Naidu K.C.B. A review on perovskite solar cells (PSCs), materials and applications. J. Materiomics, 2021, 7, P. 940–956.

2. Miah M.H., Rahman M.B., Nur-E-Alam M., Das N., Soin N.B., Hatta S.F.W.M., Islam M.A. Understanding the degradation factors, mechanism and initiatives for highly efficient perovskite solar cells. Chem. Nano Mat., 2023, 9, e202200471.

3. Green M.A., Dunlop E.D., Yoshita M., Kopidakis N., Bothe K., Siefer G., Hao X. Solar cell efficiency tables (version 62). Prog. Photovolt. Res. Appl., 2023, 31, P. 651–663.

4. Roy P., Kumar Sinha N., Tiwari S., Khare A. A review on perovskite solar cells: evolution of architecture, fabrication techniques, commercialization issues and status. Sol. Energy, 2020, 198, P. 665–688.

5. Shao J.Y., Li D., Shi J., Ma C., Wang Y., Liu X., Jiang X., Hao M., Zhang L., Liu C., Jiang Y., Wang Z., Zhong Y.W., Liu S.F., Mai Y., Liu Y., Zhao Y., Ning Z., Wang L., Xu B., Meng L., Bian Z., Ge Z., Zhan X., You J., Li Y., Meng Q. Recent progress in perovskite solar cells: material science. Sci. China Chem., 2023, 66, P. 10–64.

6. Ahmed S.F., Islam N., Kumar P.S., Hoang A.T., Mofijur M., Inayat A., Shafiullah G.M., Vo D.N., Badruddin I.A., Kamangar S. Perovskite solar cells: thermal and chemical stability improvement, and economic analysis. Mater. Today Chem., 2023, 27, 101284.

7. Zhuang J., Wang J., Yan F. Review on chemical stability of lead halide perovskite solar cells. Nano-Micro Lett., 2023, 15, 84.

8. Noh M.F.M., Teh C.H., Daik R., Lim E.L., Yap C.C., Ibrahim M.A., Ludin N.A., Yusoff Abd.R.M., Jange J., Teridi M.A.M. The architecture of the electron transport layer for a perovskite solar cell. J. Mater. Chem. C, 2018, 6, P. 682–712.

9. Wang K., Olthof S., Subhani W. S., Jiang X., Cao Y., Duan L., Wang H., Du M., Liu S. F. Novel inorganic electron transport layers for planar perovskite solar cells: progress and prospective. Nano Energy, 2020, 68, 104289.

10. Chowdhury T.A., Zafar M.A.B., Islam M.S., Shahinuzzaman M., Islam M.A, Khandaker M.U. Stability of perovskite solar cells: issues and prospects. RSC Adv., 2023, 13, P. 1787–1810.

11. Yang G., Tao H., Qin P., Ke W., Fang G. Recent progress in electron transport layers for efficient perovskite solar cells. J. Mater. Chem. A, 2016, 4, P. 3970–3990.

12. Dipta S.S., Uddin A. Stability Issues of perovskite solar cells: a critical review. Energy Technol., 2021, 9, 2100560.

13. Zhao P., Han M., Yin W., Zhao X., Kim S.G., Yan Y., Kim M., Song Y. J., Park N.G., Jung H.S. Insulated interlayer for efficient and photostable electron-transport-layer-free perovskite solar cells. ACS Appl. Mater. Interfaces, 2018, 10, P. 10132–10140.

14. Kozlova E.A., Valeeva A.A., Sushnikova A.A., Zhurenok A.V., Rempel A.A. Photocatalytic activity of titanium dioxide produced by high-energy milling. Nanosystems: Phys. Chem. Math., 2022, 13, P. 632–639.

15. Huang C., Lin P., Fu N., Liu C., Xu B., Sun K., Wang D., Zenga X., Ke S. Facile fabrication of highly efficient ETL-free perovskite solar cells with 20 % efficiency by defect passivation and interface engineering. Chem. Commun., 2019, 55, P. 2777–2788.

16. Isikgor F.H., Zhumagal S., Merino L.V.T., De Bastiani M., McCulloch I., De Wolf S. Molecular engineering of contact interfaces for highperformance perovskite solar cells. Nat. Rev. Mater., 2023, 8, P. 89–108.

17. Kozlov S.S., Alexeeva O.V., Nikolskaia A.B., Shevaleevskiy O.I., Averkiev D.D., Kozhuhovskaya P.V., Almjasheva O.V., Larina L.L. Double perovskite oxides La2NiMnO6 and La2Ni0:8Fe0:2MnO6 for inorganic perovskite solar cells. Nanosystems: Phys. Chem. Math., 2022, 13, P. 314–319.

18. Nikolskaia A.B., Vildanova M.F., Kozlov S.S., Shevaleevskiy O.I. Physicochemical approaches for optimization of perovskite solar cell performance. Russ. Chem. Bull., 69, P. 1245–1252.

19. Nikolskaia A.B., Kozlov S.S., Karyagina O.K., Alexeeva O.V., Almjasheva O.V., Averkiev D.D., Kozhuhovskaya P.V., Shevaleevskiy O.I. Cation doping of La2NiMnO6 complex oxide with the double perovskite structure for photovoltaic applications. Russ. J. Inorg. Chem., 2022, 67, P. 921–925.

20. Han G., Zhang S., Boix P.P., Wong L.H., Sun L., Lien S.-Y. Towards high efficiency thin film solar cells. Progr. Mater. Sci., 2017, 87, P. 246–291.

21. Sheikh M.S., Sakhya A.P., Dutta A., Sinha T.P. Light induced charge transport in La2NiMnO6 based Schottky diode. J. Alloy. Comp., 2017, 727, P. 238–245.

22. Tauc J., Grigorovici R., Vancu A. Optical properties and electronic structure of amorphous germanium. Phys. Status Solidi, 1966, 15, P. 627–637.


Review

For citations:


Kozlov S.S., Nikolskaia A.B., Karyagina O.K., Kosareva E.K., Alexeeva O.V., Petrova V.I., Almjasheva O.V., Shevaleevskiy O.I. Planar perovskite solar cells with La2NiMnO6 buffer layer. Nanosystems: Physics, Chemistry, Mathematics. 2023;14(5):584-589. https://doi.org/10.17586/2220-8054-2023-14-5-584-589

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ISSN 2220-8054 (Print)
ISSN 2305-7971 (Online)