Нанокомпозиты ароматического полиамидоимида с нанотубулярным Mg-Fe-гидросиликатом

Композитные пленки на основе ароматического полиамидоимида с карбоксилсодержащими фрагментами в повторяющихся звеньях (ПАИ-Ас), содержащие гидросиликатные нанотрубки (Mg,Fe)₃Si₂O₅(OH)₄, структурно чувствительны к молекулярной массе используемого полимера. По данным мёссбауэровской спектроскопии, нанотрубки, введенные в полимерную матрицу, как правило, сохраняют свою первоначальную структуру. При использовании полимера с относительно низкой молекулярной массой образуются композитные пленки, нестабильные при первапорации циклогексана и этанола. В случае высокомолекулярного полимера полученные мембраны стабильны при первапорации. Они более проницаемы для полярных жидкостей по сравнению с базовым полимером и композиционными мембранами, содержащими нанотрубки Mg₃Si₂O₅(OH)₄. Анализ обнаруженных отличий свойств исследованных нанокомпозитов с железосодержащими нанотрубками в матрице ПАИ-Ак от аналогичных нанокомпозитов с магнийсодержащими нанотрубками позволяет сделать вывод о необходимости изучения композиционных мембран с железосодержащими наночастицами другой структуры.

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