Sorption of polar and non-polar liquids by GO powders according to DSC experiments
https://doi.org/10.17586/2220-8054-2024-15-1-130-134
Abstract
The sorption properties of Hummers (HGO) and Brodie (BGO) graphite oxides with respect to various liquids were studied by the DSC method. In the case of HGO, the reduced material (RHGO) was obtained by hydrothermal synthesis. The effective reduction of the material was confirmed by XRD. The difference in the sorption of water and acetonitrile by HGO and RHGO was experimentally observed. The DSC experimental procedure was developed to estimate the selective sorption of the component from the immisible liquid mixtures. The procedure has been tested on the sorption of the water-octane mixture by HGO. It was shown that water can be sorbed by HGO from the mixture in an amount equal to equilibrium sorption of pure water by HGO at 273 K. The results obtained will serve as the basis for further studies of the sorption properties of GO.
Supporting agencies: The study was supported by the Russian Science Foundation (RSF 22-29-00544)
About the Authors
A. V. Kaplin
Moscow State University; Semenov Federal Research Center of Chemical Physics, Russian Academy of Sciences
Russian Federation
Russian Federation
Alexander V. Kaplin – MSU, Chemistry Department, Moscow; Semenov Federal Research Center of Chemical Physics, RAS.
Moscow
E. A. Eremina
Moscow State University
Russian Federation
Russian Federation
Elena A. Eremina –Chemistry Department.
Moscow
M. V. Korobov
Moscow State University
Russian Federation
Russian Federation
Mikhail V. Korobov –Chemistry Department.
Moscow
References
1. Paredes J.I., Villar-RodilS., Mart´ınez-Alonso A., Tasco´n J.M.D. Graphene Oxide Dispersions in Organic Solvents. Langmuir, 2008, 24, P. 10560– 15604.
2. Korobov M.V., Talyzin A.V., Rebrikova A.T., Shilayeva E.A., Avramenko N.V., Gagarin A.N., Ferapontov N.B. Sorption of polar organic solvents and water by graphite oxide: Thermodynamic approach. Carbon, 2016, 102, P. 297–303.
3. Dreyer D.R., Park S., Bielawski C.W., Ruoff R.S. The chemistry of graphene oxide. Chemical Society Review, 2010, 39, P. 228–240.
4. Ferrari A.C., Bonaccorso F., Falko V. Science and technology roadmap for grapheme related two-dimensional crystals, and hybrid systems. Nanoscale, 2015, 7, P. 4598–4810.
5. Brodie B.C. On the atomic weight of graphite. Philosophical Transactions of the Royal Society of London, 1859, 149, P. 249–259.
6. Hummers W.S., Offeman R.E. Preparation of graphitic oxide. J. of the American Chemical Society, 1958, 80, P. 1339–1343.
7. Higginbotham A.L., Kosynkin D.V., Sinitskii A., Sun Z., Tour J.M. Lower – Defect Graphene Oxide Nanoribbons from Multiwalled Carbon Nanotubes. ASC Nano, 2010, 4, P. 2059–2069.
8. Talyzin A.V., Mercier G., Klechikov A., Hedenstrom M., Johnels D., Wei D., Cotton D., Opitz A., Moons E. Brodie vs Hummers graphite oxides for preparation of multi-layered materials. Carbon, 2017, 115, P. 430–440.
9. Kaplin A.V., Rebrikova A.T., Eremina E.A., Chumakova N.A., Avramenko N.V., Korobov M.V. Sorption of Polar Sorbents into GO Powders and Membranes. Membranes, 2023, 53 (13), P. 1–12.
10. Liu X.L., Ma R., Wang X.X., Ma Y., Yang Y.P., Zhuang L., Zhang S., Jehan R., Chen J.R., Wang X.K. Prepared GO functionalized with lignosulfonate (LS) and polyaniline (PANI) for the adsorption of Pb ions. Environ. Pollut., 2019, 252, P. 62–73.
11. Romanchuk A.Y., Slesarev A.S., Kalmykov S.N., Kosynkin D.V., Tour J.M. Graphene oxide for effective radionuclide removal. Phys. Chem. Chem. Phys., 2013, 15, P. 2321–2327.
12. Kuzenkova A.S., Romanchuk A.Y., Trigub A.L., Maslakov K.I., Egorov A.V., Amidani L., Kittrell C., Kvashnina K.O., Tour J.M., Talyzin A.V., Kalmykov S.N. New insights into the mechanism of graphene oxide and radionuclide interaction. Carbon, 2020, 158, P. 291–302.
13. Szabo T., Berkesi O., Forgo P., Josepovits K., Sanakis Y. Evolution of Surface Functional Groups in a Series of Progressively Oxidized Graphite Oxides. Chemistry of Materials, 2006, 18, P. 2740–2749.
14. Rebrikova A.T., Klechikov A., Iakunkov A., Sun J., Talyzin A.V., Avramenko N.V., Korobov M.V. Swollen Structures of Brodie Graphite Oxide as Solid Solvates. J. Phys. Chem. C, 2020, 124, P. 23410–23418.
15. Marcus Y., Smith A.L., Korobov M.V., Mirakyan A.L., Avramenko N.V., Stukalin E.B. Solubility of C60 Fullerene. J. Phys. Chem. B, 2001, 105, P. 2499–2506.
16. Vipul Agarwal, Per B. Zetterlund Strategies for reduction of graphene oxide – A comprehensive review. Chemical Engineering J., 2019, 405, 12708.
17. Iakunkov A., Skrypnychuk V., Nordenstro A., Shilayeva E.A., Korobov M., Prodana M., Enachescu M., Larssond S.H., Talyzin A.V. Activated graphene as a material for supercapacitor electrodes: effects of surface area, pore size distribution and hydrophilicity. Physical Chemistry Chemical Physics, 2019, 21, P. 17901–17912.
18. Barroso-Bujans F., Cerveny S., Alegrıa A., Colmenero J. Sorption and desorption behavior of water and organic solvents from graphite oxide. Carbon, 2010, 48, P. 3277–3286.
Review
For citations:
Kaplin A.V., Eremina E.A., Korobov M.V. Sorption of polar and non-polar liquids by GO powders according to DSC experiments. Nanosystems: Physics, Chemistry, Mathematics. 2024;15(1):130-134. https://doi.org/10.17586/2220-8054-2024-15-1-130-134
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