Solution processed Ag–In–S nanoparticles as light adsorber in ZnO for photovoltaic application
https://doi.org/10.17586/2220-8054-2023-14-4-454-466
Abstract
Nano-sized indium incorporated silver sulphide (Ag–In–S) nanocomposites were synthesized by simple wet chemical method as an electron transport layer in zinc oxide (ZnO) for high efficient photovoltaic (PV) cell. The inclusion of high conductivity indium ions in Ag2S will improve the facile electron transfer and the assembled hetero-structure features the solar light harvesting in PV cell. The powder X-ray diffraction (XRD) studies confirmed the formation of indium incorporated Ag2S (AIS) nanocomposites and ZnO/AIS (ZAIS) compound nanocomposites crystallizing in pure monoclinic phase and mixed wurtzite hexagonal, monoclinic and tertiary phases respectively. The wide particle size distributions in ZAIS clearly revealed the adherence of AIS nanocomposites in ZnO lattice thus, promoting the light adsorption property. In addition, the tuning of the optical bandgap covering the entire solar spectrum (UV, visible, and infra-red regions), multiple-band electron transitions and hence, promoting the fast electron transportation are effectively achieved in ZAIS compound nanocomposites. With this simple positive approach, the PV cell efficiency is pushed forward with the In3+ metal ion incorporation however; enhanced, enriched solar cell efficiency can be later tuned up with the detailed optimization studies
Keywords
Supporting agencies: We acknowledge Hindustan Institute of Technology and Science for the financial assistance through HITS Seed Money Grant 2023 SEED/CRC/HITS/2022-23/0013. We owe a deep sense of gratitude to Prof. Dr. R. Jayavel, Former Dean, ACT campus and all the research scholars, Centre for Nanoscience and Technology, Anna University, Chennai for ensuring the facilities and instruments available in the laboratory
About the Authors
K. Abinaya
London South Bank University
United Kingdom
United Kingdom
K. Abinaya – Doctoral Researcher
London SE1 0AA, UK
P. Sharvanti
Research and Development
United States
United States
P. Sharvanti – Senior Process Engineer,
Saint Gobain, San Diego, California 92123
N. Rajeswari Yogamalar
Hindustan Institute of Technology and Science
India
India
N. Rajeswari Yogamalar – Department of Physics,
Padur, Kelambakkam, Chennai – 603103
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Review
For citations:
Abinaya K., Sharvanti P., Rajeswari Yogamalar N. Solution processed Ag–In–S nanoparticles as light adsorber in ZnO for photovoltaic application. Nanosystems: Physics, Chemistry, Mathematics. 2023;14(4):454-466. https://doi.org/10.17586/2220-8054-2023-14-4-454-466
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